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Chalk with drying agent (Read 6614 times)

mark20

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#25 Re: Chalk with drying agent
January 06, 2023, 07:58:11 pm
Would be super interesting to hear how you get on with this. Best case is DIY friction labs type chalk for, presumably, much less £££.
Not quite - FrictionLabs is "pure" Magnesium Carbonate with no drying agents or additives. Looking at the analysis in the link from the first post, looks like the Metolius stuff is too, but with 0.5% SiO2 added.
I've never used FrictionLabs but looking at that I'm not sure what the hype is - maybe it has been dried better so has less water content? Plenty of reputable folk on here say they notice a difference though.

Misha, you're right and anti-hydral really helps, but for me doesn't totally stop sweating especially on a long session, mincing my squidgy digits into pebbly grit holds. I'm certain I get an extra few % with the old Metolius chalk.

My SiO2 arrived today, so will begin my experiments in the coming days and report back.



mrjonathanr

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#26 Re: Chalk with drying agent
January 06, 2023, 10:24:08 pm

Not quite - FrictionLabs is "pure" Magnesium Carbonate with no drying agents or additives. Looking at the analysis in the link from the first post, looks like the Metolius stuff is too, but with 0.5% SiO2 added.
I've never used FrictionLabs but looking at that I'm not sure what the hype is - maybe it has been dried better so has less water content?


When crystals are created from a solution there is a quantity of water bonded in. It’s a long time since my school chemistry, and no doubt there are much better informed posters who could advise, but I expect your explanation may lie in the water of crystallisation.

Will Hunt

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#27 Re: Chalk with drying agent
January 07, 2023, 12:21:38 am
Not quite - FrictionLabs is "pure" Magnesium Carbonate with no drying agents or additives. Looking at the analysis in the link from the first post, looks like the Metolius stuff is too, but with 0.5% SiO2 added.

I've been led to believe that while many brands claim to be pure magnesium carbonate, very few (none?) actually are. They all have varying "purities" (not sure if that's the right word. I'm not a chemist).

remus

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#28 Re: Chalk with drying agent
January 07, 2023, 08:12:13 am
I've been led to believe that while many brands claim to be pure magnesium carbonate, very few (none?) actually are. They all have varying "purities" (not sure if that's the right word. I'm not a chemist).

Frankly I think the friction labs marketing about purity is bollocks. If you want high purity magnesium carbonate you can buy it from chemical suppliers (and pretty cheaply too), it tends to come as a very finely textured powder though which feels whack. Im pretty unconvinced that having chalk that is 99.9% MgCO3 rather than 99.5% makes any noticeable difference.

If there is anything substantially different about friction labs I suspect it's to do with the texture of it. Perhaps they put some more effort in to getting a nice mix of grain sizes compared to other manufacturers? (Apologies to anyone who knows the correct technical terms for this stuff, Im sure Im butchering it).

mrjonathanr

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#29 Re: Chalk with drying agent
January 07, 2023, 10:01:37 am
Talking about MgCO3 suggests chalk is composed of discrete magnesium carbonate molecules. As far as I can see, this isn’t what you get in climbing chalk, but MgCO3 bonded to water. As an example, google throws up this research paper. https://journals.iucr.org/c/issues/2020/03/00/lg3251/lg3251.pdf

The first paragraph outlines the conversion of Magnesium Carbonate Hexahydrate MgCO3-6H2O to Magnesium Carbonate Trihydrate MgCO3-3H2O. Clearly differing crystals which I’d expect to have some differing properties. There must be considerable variation possible in how many water molecules are bonded to the magnesium carbonate in your sweaty paws.

Any chemists willing to enlighten us?

Will Hunt

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#30 Re: Chalk with drying agent
January 10, 2023, 09:19:10 am
Absolute snow confirmed they have the old stuff, i ordered 4 bags, free postage.

https://www.absolute-snow.co.uk/V/Metolius_Super_Chalk_Rock_Climbing_Chalk_127g-(71863)


Just received my delivery. It's the new stuff. Hopefully it's not shit.

Eddies

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mark20

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#32 Re: Chalk with drying agent
January 10, 2023, 01:35:59 pm
Great info, thanks. I'm surprised I hadn't heard of upsalite before, looks like Black Diamond sell it https://www.bananafingers.co.uk/chalk/black-diamond/pure-gold-upsalite-chalk
Pricey, but could be good for redpoints.

I will have to get some and compare with the SiO2.


I did a little experiment whilst fingerboarding a couple of days ago.
Metolius superchalk in one chalk bag, Metolius superchalk + SiO2 drying agent in the other.
I cocked up my ratio and the mix is about 10% drying agent, rather than the 0.5%ish in the original Superchalk.

The difference between the two was very noticeable. It was bad conditions in the cellar, mild and humid. Doing repeaters on wooden holds, the plain chalk was getting damp and needed brushing off between repeaters, and chalk slapped back on again for another set.
But on the drying agent hand, the hold stayed dry and chalked and the hand was clearly much drier and didn't really need to put more chalk back on.
Actually, on wooden holds in humid conditions, the slightly damp plain chalk felt a bit better, almost 'sticky damp'.
But I suspect outside, especially on grit, the drying agent chalk will feel a lot better as it feels as though it is actively drying the skin. I definitely wanted to wash my hands straight away after my session. The main finding was that the drying agent does work, I just need to tweak my ratios and test on some rock

sdm

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#33 Re: Chalk with drying agent
January 10, 2023, 01:55:51 pm
I'll be interested to hear how people get on with upsalite.

Black Diamond have been selling white gold / black gold for a few years now.

My assumption is that you would hear people raving about it if it was as effective as the claims. I've never heard anybody raving about it so I've assumed it's not worth the money. I haven't tested it for myself though.

Maybe Black Diamond need to hire the Friction Labs marketing guys.

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#34 Re: Chalk with drying agent
January 10, 2023, 03:15:16 pm
Nothing would surprise me more than learning that MgO3 does not absorb enough water to dry out my hands, and that I would get dryer hands quicker and therefore climb harder by applying some other salt. This other salt also would need to have same or better rolling resistance when placed between rock and a sweaty hand.

I have super sweaty hands and have never found any difference between brands. I just buy the cheapest available that has a decent crunchiness/ease of application. Have I missed a trick? Could I climb 8c by just forking out some more of my hard earned euros?

Fultonius

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#35 Re: Chalk with drying agent
January 10, 2023, 04:06:20 pm
I take it you've tried anti-hydral / other skin drying agents?

SA Chris

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#36 Re: Chalk with drying agent
January 10, 2023, 05:02:10 pm
Absolute snow confirmed they have the old stuff, i ordered 4 bags, free postage.

https://www.absolute-snow.co.uk/V/Metolius_Super_Chalk_Rock_Climbing_Chalk_127g-(71863)


Just received my delivery. It's the new stuff. Hopefully it's not shit.

See later comment, they got it all wrong, very apologetic, but at least they do free returns.

jwi

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#37 Re: Chalk with drying agent
January 10, 2023, 06:17:15 pm
I take it you've tried anti-hydral / other skin drying agents?

I cannot use anti-hydral as I have very very thick skin, and that just makes it worse

mark20

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#38 Re: Chalk with drying agent
July 08, 2023, 11:42:09 am
Update 6 months on,
I've been using it at about 2%-5% ish, grit bouldering and more recently limestone and it definitely helps actually dry the skin. I often chalk up when resting and can feel the skin actually dry out a bit and feel good again for climbing. Like the original superchalk, the benefits are more noticable on gritstone where skin condition is a bit factor for me. I've given drying agent to a few mates gineau pigs and all have neutral or slightly positive experiences, Haydn is a big fan and has gone through about 500g of the stuff! No ill effects yet

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#39 Re: Chalk with drying agent
July 08, 2023, 12:32:28 pm
Are you basically adding silicon crystals to your chalk?

mark20

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webbo

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#41 Re: Chalk with drying agent
July 08, 2023, 01:20:46 pm
Yes as a fine powder, from here
https://www.claymansupplies.co.uk/Products/Details/5165~500
I like the bit where it says The dust is extremely hazardous  ☢️

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#42 Re: Chalk with drying agent
July 08, 2023, 01:26:07 pm
Yes as a fine powder, from here
https://www.claymansupplies.co.uk/Products/Details/5165~500
I like the bit where it says The dust is extremely hazardous  ☢️

Seconding this, silcosis is pretty bad and irreversible so I'd avoid over use
https://www.nhs.uk/conditions/silicosis/

Nike Air

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#43 Re: Chalk with drying agent
July 10, 2023, 10:39:27 pm
Yes as a fine powder, from here
https://www.claymansupplies.co.uk/Products/Details/5165~500

Thanks. I notice after purifying water at work through a similar product my hands get incredibly dry, almost too dry.

mark20

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#44 Re: Chalk with drying agent
July 12, 2023, 11:35:11 am
As mentioned a few times, it seems this stuff can be quite nasty. As a precaution, I take care to pour it in very gently when adding it to my chalk bag and then close it and shake to mix it in. I use a separate chalk bag without the drying agent in for training in the cellar or on the rare occasion I go to a climbing wall
I'm fairly happy that exposure is minimal
I also wonder if that once it is in the chalk bag and mixed up, it will bond with the chalk so forms larger dust particles which will be more easily removed / less dangerous in the lungs ??

Dingdong

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#45 Re: Chalk with drying agent
July 12, 2023, 01:41:31 pm
I can’t lie, I wouldn’t chance it just to have dry hands when there’s definitely other safer alternatives…

SA Chris

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Will Hunt

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#47 Re: Chalk with drying agent
July 12, 2023, 04:16:08 pm
I've been using the new super chalk which apparently doesn't have the drying agent that was in the old stuff. I haven't noticed any difference in how well it works so don't see a need to be taking a risk with dodgy powders.

In the words of a climbing chemist friend who runs a university geology lab and knows about materials hazards:
"https://ukbouldering.com/board/index.php/topic,33364.msg679374.html#msg679374 this might actually be some of the dumbest fucking shit I’ve seen in climbing

At least he’s not using it indoors so the only person he’s going to fuck up is most likely himself

Silicosis can cripple you, it’s not dissimilar to asbestosis but you’re unlikely to actually die from it

I quite often get small clouds of chalk dust in my face when chalking up/removing excess. They’ll be breathing in the silica dust whenever they do that…

It may well be ok. Personally I wouldn’t take the risk. I’d like my lungs to keep functioning so that I can keep climbing/doing stuff into old age rather than being bedridden, sucking on an oxygen cylinder to get enough breath just to say a few words all so I could have slightly less sweaty hands in my 30s."
« Last Edit: July 12, 2023, 04:21:38 pm by Will Hunt »

i.munro

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#48 Re: Chalk with drying agent
July 13, 2023, 12:59:55 pm
Is nobody going to mention the fact that this is not only a personal risk?
Even if used only outside others will inevitably be breathing this crap when brushing holds.
There is also the effect on the rock to consider. Short-term it will absorb moisture from the air turning into a slimy mess. - long term we have no information what damage it might do.

mark20

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#49 Re: Chalk with drying agent
July 13, 2023, 02:49:41 pm
this might actually be some of the dumbest fucking shit I’ve seen in climbing
Really? It's the same stuff that has been in Superchalk for years.

There is also the effect on the rock to consider. Short-term it will absorb moisture from the air turning into a slimy mess. - long term we have no information what damage it might do.
20+ (?) years of superchalk use, and probably others.
At <5% mix I can't imagine it turning into any more slimy mess than normal chalk. Possible less so, as less chalk required!

I'm not too concerned about the risk from inhalation, as I can minimise that. But the skin contact theory post by SA Chris is interesting. Perhaps I should cut out all the shampoos, deodrants and foods (!) that use it as an additive as well.

 

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